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Project: NORTE-01-0145-FEDER-028538

Project name: DEMOM - Defect-engineering in rare-earth nickelate thin films towards active magnetic and optical metamaterials
Project code: NORTE-01-0145-FEDER-028538
Intervention Region: Norte
Proposing institution/Lead promoter/Coordinating entity: Faculdade de Ciências da Universidade do Porto
Partner(s)/Co-promoter(s)/Participating institution(s): Universidade de Trás-os-Montes e Alto Douro; Universidade do Minho
Date of approval: 2018-04-04
Start date: 2018-07-01
Completion date: 2022-04-30
Eligible Cost of the Project
Total Eligible Cost: 239.544,89 EUR
Total Financial Support
União Europeia - FEDER: 203.188,16 EUR
Orçamento de Estado: 35.856,73 EUR
Objectives, activities and expected/achieved results
The main idea of this project is to induce changes on the metal-insulator transition
(MIT), magnetic and electronic properties of RNiO3 (R=Sm, Nd) thin films by defectengineering
through intentional creation of oxygen vacancies and spatially-selective
defects by ion irradiation, towards active photonic structures and optical metamaterials.
In this field, rare-earth nickelates (RNO) are outstanding phase transition materials for
the coupling between spin, charge, orbital and lattice degrees of freedom, yielding a
wide range of physical properties. The electronic, magnetic and transport properties of
RNO are known to be very sensitive to even subtle changes in Ni-O-Ni bond angles due
to lattice defects and strain, making them promising materials for multifunctional smart
devices. In this proposal, multifunctionality will be accessed via deliberately inserting
oxygen vacancies by annealing, and spatially defects by ion irradiation.
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