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Thermochemical study of chloropyrazines and chloroquinoxalines

Title
Thermochemical study of chloropyrazines and chloroquinoxalines
Type
Article in International Scientific Journal
Year
2004
Authors
Morais, VMF
(Author)
ICBAS
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Miranda, MS
(Author)
Other
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Matos, MAR
(Author)
FCUP
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Journal
Vol. 36
Pages: 377-383
ISSN: 0021-9614
Publisher: Elsevier
Scientific classification
FOS: Engineering and technology > Mechanical engineering
Other information
Authenticus ID: P-000-AJP
Abstract (EN): The standard (pdegrees = 0.1 MPa) molar enthalpies of formation for liquid 2-chloropyrazine and crystalline 2,6-dichloropyrazine, 2,3-dichloroquinoxaline and 2,3,6,7-tetrachloroquinoxatine were derived from the standard molar enthalpies of combustion, in oxygen, to yield CO(2)(g), N(2)(g), and HCl . 600H(2)O(l), at the temperature T = 298.15 K, measured by rotating-bomb combustion calorimetry. The standard molar enthalpies of vaporization or of sublimation, at T = 298.15 K, were measured by Calvet microcalorimetry.
Language: English
Type (Professor's evaluation): Scientific
Contact: marmatos@fc.up.pt
No. of pages: 7
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