Phase Competitions behind the Giant Magnetic Entropy Variation: Gd5Si2Ge2 and Tb5Si2Ge2 Case Studies

• Type: Another Publication in an International Scientific Journal
• Date: 2014

Authors

Pires, AL (Author) Other; Belo, JH (Author) Other; Lima Lopes, AML (Author) Other; Gomes, IT (Author) Other; Morellon, L (Author) Other; Magen, C (Author) Other; Antonio Algarabel, PA (Author) Other; Ricardo Ibarra, MR (Author) Other; pereira, a. m. (Author) FCUP; araujo, j. p. (Author) FCUP

Journal

Title: Entropy

Vol. 16

Pages: 3813-3831

ISSN: 1099-4300

Publisher: MDPI

Indexing

ISI Web of Knowledge - 16 Citations

Scopus - 16 Citations

Other information

Authenticus ID: P-009-RNF

DOI: 10.3390/e16073813

Abstract (EN): Magnetic materials with strong spin-lattice coupling are a powerful set of candidates for multifunctional applications because of their multiferroic, magnetocaloric (MCE), magnetostrictive and magnetoresistive effects. In these materials there is a strong competition between two states (where a state comprises an atomic and an associated magnetic structure) that leads to the occurrence of phase transitions under subtle variations of external parameters, such as temperature, magnetic field and hydrostatic pressure. In this review a general method combining detailed magnetic measurements/analysis and first principles calculations with the purpose of estimating the phase transition temperature is presented with the help of two examples (Gd5Si2Ge2 and Tb5Si2Ge2). It is demonstrated that such method is an important tool for a deeper understanding of the (de) coupled nature of each phase transition in the materials belonging to the R-5(Si,Ge)(4) family and most possibly can be applied to other systems. The exotic Griffiths-like phase in the framework of the R-5(SixGe1-x)(4) compounds is reviewed and its generalization as a requisite for strong phase competitions systems that present large magneto-responsive properties is proposed.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 19