Catalytic Hydrogenation of Nitrate over Immobilized Nanocatalysts in a Multi-Phase Continuous Reaction System: System Performance, Characterization and Optimization

• Tipo: Artigo em Revista Científica Internacional
• Data: 2023

Autores

Santos, ASGG (Autor) Outra; Restivo, J (Autor) Outra; Carla Orge (Autor) FEUP; Manuel Fernando R Pereira (Autor) FEUP; O.S.G.P. Soares (Autor) FEUP

Revista

A Revista está pendente de validação pelos Serviços Administrativos.

Título: PROCESSES

Vol. 9 Nº 1

Página Final: 2692

ISSN: 2227-9717

Indexação

ISI Web of Knowledge - 0 Citações

Scopus - 0 Citações

Projetos Associados

LA LSRE-LCM - Financiamento Plurianual 2020-2023 para a Unidade LA LSRE-LCM Laboratório de Processos de Separação e Reacção - Laboratório de Catálise e Materiais

Outras Informações

ID Authenticus: P-00Z-0RE

DOI: 10.3390/pr11092692

Abstract (EN): Nitrate catalytic reduction in a continuous system was studied in the presence of Pd-Cu macrostructured catalysts synthesized through a novel washcoating methodology of the pre-formed bimetallic powder catalyst. The present work aims to understand the behavior of the macrostructured bimetallic catalyst in the presence of different reaction conditions in order to achieve the design of an optimized facility that can produce the best catalytic results: maximum NO3- conversion with enhanced N2 selectivity. The residence time of the inlet solution and the catalyst concentration in the reactor proved to be the parameters that most influenced the conversion and selectivity due to the important role that these parameters play in the hydrodynamic conditions of the reactor. A higher loading of catalyst and lower inlet flow rates allow promoting a higher contact time between the three phases that participate in the reaction (G-L-S). The most efficient reaction conditions (three pieces of the macrostructured catalyst, liquid flow rate of 10 mL min-1, and a total gas flow rate of 200 Ncm3 min-1 (1:1 H2:CO2)) allowed obtaining an NO3- conversion of 51% with a corresponding N2 selectivity of 23%. Also, the conversion results strongly depended on the total gas flow rate used during the reaction since this assists the mixing between the three phases and promotes a greater contact that will contribute to enhanced catalytic results.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 19