Development of a Facile and Green Synthesis Strategy for Brightly Fluorescent Carbon Dots from Various Waste Materials

• Tipo: Artigo em Revista Científica Internacional
• Data: 2024

Autores

Fernandes, S (Autor) Outra; Algarra, M (Autor) Outra; Gil, A (Autor) Outra; Joaquim C G E Esteves da Silva (Autor) FCUP; da Silva, LP (Autor) FCUP

Revista

Título: ChemSusChem

Vol. 18

ISSN: 1864-5631

Editora: Wiley-Blackwell

Indexação

ISI Web of Knowledge - 4 Citações

Scopus - 3 Citações

Outras Informações

ID Authenticus: P-017-PWQ

DOI: 10.1002/cssc.202401702

Abstract (EN): Carbon dots (CDs) are fluorescent carbon-based nanomaterials with remarkable properties, making them more attractive than traditional fluorophores. Consequently, researchers focused on their development and application in fields such as sensing and bioimaging. One potential advantage of employing CDs is using organic waste as carbon precursors in their synthesis, providing a pathway for waste upcycling for a circular economy. However, waste-based CDs often have low fluorescence quantum yields (QY(FL)), limiting their practical applications. So, there is a need for a well-defined strategy to consistently produce waste-based CDs with appreciable QY(FL), irrespective of the starting waste material. Herein, we developed a fabrication strategy based on the hydrothermal treatment of waste materials, using citric acid as a co-carbon precursor and ethylenediamine as N-dopant. This strategy was tested with various materials, including corn stover, spent coffee grounds, cork powder, and sawdust. The results showed consistently appreciable QY(FL), reaching up to similar to 40 %. A Life Cycle Assessment (LCA) study demonstrated that producing these waste-based CDs has lower environmental impacts compared to CDs made solely from commercial reagents. Thus, we have established a framework for the environmentally friendly production of CDs by upcycling different waste materials without significant sacrifices in performance (QY(FL)).

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 11