Mixture effects during the oxidation of toluene, ethyl acetate and ethanol over a cryptomelane catalyst

• Tipo: Artigo em Revista Científica Internacional
• Data: 2011

Autores

Vera Santos (Autor) FEUP; M. F. R. Pereira (Autor) FEUP; J. J. M. Orfão (Autor) FEUP; J. L. Figueiredo (Autor) FEUP

Revista

Título: Journal of Hazardous Materials

Vol. 185

Páginas: 1236-1240

ISSN: 0304-3894

Editora: Elsevier

Indexação

ISI Web of Knowledge - 20 Citações

ISI Web of Science

Scopus - 31 Citações

Classificação Científica

FOS: Ciências da engenharia e tecnologias > Engenharia química

Outras Informações

ID Authenticus: P-002-VRD

DOI: 10.1016/j.jhazmat.2010.10.036

Abstract (EN): The catalytic oxidation of two-component VOC mixtures (ethanol, ethyl acetate and toluene) was studied over cryptomelane. Remarkable mixture effects were observed on the activity and the selectivity. Toluene inhibits both ethyl acetate and ethanol oxidation, this effect being more evident in the case of ethyl acetate. For instance, the temperature for 100% conversion is about 210 degrees C when ethyl acetate is oxidised alone, and 250 degrees C or higher, when it is oxidised in mixtures with toluene. On the contrary, toluene oxidation is only slightly inhibited by the presence of ethyl acetate, while the presence of ethanol has a promoting effect. Concerning the mixtures of ethyl acetate and ethanol, both compounds have a mutual inhibitory effect, which is more evident in the case of ethyl acetate (the temperature for 100% conversion of ethyl acetate is about 45 degrees C higher when ethyl acetate is oxidised in mixtures with ethanol, while in the case of ethanol the corresponding increase is only 10 degrees C).

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 5