Photocatalytic oxidation of gaseous perchloroethylene over TiO2 based paint

• Tipo: Artigo em Revista Científica Internacional
• Data: 2015

Autores

Ricardo A. R. Monteiro (Autor) FEUP; Adrián M. T. Silva (Autor) FEUP; Joana R. M. Ângelo (Autor) FEUP; Gabriela V. Silva (Autor) FEUP; Adélio M. Mendes (Autor) FEUP; Rui A. R. Boaventura (Autor) FEUP; Vítor J. P. Vilar (Autor) FEUP

Revista

Título: Journal of Photochemistry and Photobiology A: Chemistry

Vol. 311

Páginas: 41-52

ISSN: 1010-6030

Editora: Elsevier

Indexação

ISI Web of Knowledge - 13 Citações

ISI Web of Science

Scopus - 21 Citações

Classificação Científica

FOS: Ciências da engenharia e tecnologias > Engenharia do ambiente

CORDIS: Ciências Tecnológicas > Tecnologia > Tecnologia ambiental

Projetos Associados

LSRE-LCM - Laboratório de Processos de Separação e Reação - Laboratório de Catálise e Materiais

LEPABE - Laboratório de Engenharia de Processos, Ambiente, Biotecnologia e Energia

Outras Informações

ID Authenticus: P-00G-BV0

DOI: 10.1016/j.jphotochem.2015.06.007

Abstract (EN): Perchloroethylene (PCE) is a volatile chlorinated compound persistently present in indoor air of several industrial closed facilities. Due to its environmental and human health impact, efforts have been directed in the last decades toward the degradation of this kind of air pollutants. The photocatalytic oxidation (PCO) of PCE was studied in an annular photoreactor equipped with a compound parabolic collector (CPC) and employing two different configurations of a monolithic structure of cellulose acetate coated with an active TiO2-based paint (9 wt.% of TiO2 PC500) under solar radiation. The influence of the experimental conditions, namely feed flow rate (Q(feed)), initial concentration (C-PCE,C-feed), relative humidity (RH) in the system, absence of oxygen and incident irradiance on the PCE conversion was evaluated. Under the best experimental conditions (C-PCE,C-reed = 1100 ppm, Q(feed) = 75 cm(3) min(-1), RH = 40% and I = 38.4 W-UV m(-2) in the presence of oxygen) 60% of the initial PCE concentration was converted. The results showed that depending on the configuration of the structure, photocatalytic degradation of PCE can be enhanced by approximately 58%. Results obtained at low RH suggest that Cl radical chain propagation reactions may be included in the PCO mechanism of PCE. Also, in the absence of oxygen the photoreaction can still take place.

Idioma: Inglês

Tipo (Avaliação Docente): Científica

Nº de páginas: 12