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Oxidovanadium(IV) Complexes of 3-Hydroxy-4-pyrone and 3-Hydroxy-4-pyridinone Ligands: A New Generation of Homogeneous Catalysts for the Epoxidation of Geraniol

Title
Oxidovanadium(IV) Complexes of 3-Hydroxy-4-pyrone and 3-Hydroxy-4-pyridinone Ligands: A New Generation of Homogeneous Catalysts for the Epoxidation of Geraniol
Type
Article in International Scientific Journal
Year
2010
Authors
Andreia Leite
(Author)
Other
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Ana Nunes
(Author)
Other
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Susana L H Rebelo
(Author)
FCUP
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Journal
Title: Catalysis LettersImported from Authenticus Search for Journal Publications
Vol. 135 No. 1-2
Pages: 98-104
ISSN: 1011-372X
Publisher: Springer Nature
Scientific classification
FOS: Natural sciences > Chemical sciences
Other information
Authenticus ID: P-003-8FV
Abstract (EN): A novel generation of homogeneous catalysts for the epoxidation of geraniol, in the presence of tert-butyl hydroperoxide oxidant is reported. Oxidovanadium(IV) complexes of 3-hydroxy-4-pyrone and 3-hydroxy-4-pyridinone ligands exhibit excellent activity and selectivity towards the 2,3-epoxygeraniol product, only differing in the reaction times and turnover frequencies. The pyrone based complexes are the most efficient catalysts showing performances similar to that of the well known oxidovanadium(IV) acetylacetonate catalyst.
Language: English
Type (Professor's evaluation): Scientific
Contact: acfreire@fc.up.pt
No. of pages: 7
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