Microwave-assisted synthesis of carbon dots and its potential as analysis of four heterocyclic aromatic amines

• Type: Article in International Scientific Journal
• Date: 2015

Authors

Lopez, C (Author) Other; Zougagh, M (Author) Other; Algarra, M (Author) Other; Rodriguez Castellon, E (Author) Other; Campos, BB (Author) Other; Esteves C G E da Silva (Author) FCUP; Jimenez Jimenez, J (Author) Other; Rios, A (Author) Other

Journal

Title: Talanta

Vol. 132

Pages: 845-850

ISSN: 0039-9140

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 54 Citations

Scopus - 60 Citations

Scientific classification

FOS: Natural sciences > Chemical sciences

Other information

Authenticus ID: P-009-Y39

DOI: 10.1016/j.talanta.2014.10.008

Abstract (EN): Fluorescent water soluble carbon nanoparticles, in short carbon dots (CDs), was synthesized from lactose by microwave assisted hydrochloric acid method. Characterized by TEM and DLS to obtain the morphology shape (average 10 nm in size), with a higher negative surface charge supported by the composition was obtained by XPS spectroscopy. The maximum of the emission was centered at 450 nm with a lifetime of 2.1 ns. Without further functionalization of the CDs a nanosensor was obtained that responded exponentially to HAAs in the 0.35-0.45 mg L-1 concentration range by fluorescence static quenching, demonstrated by the lifetime analysis of the CDs in presence of HAAs. Some amino compounds were selected as model for interferences to evaluate the selectivity of this method, showing a notorious added value, with recoveries around 98%. The accuracy of the method was in terms of RSD about 2.5%. The results suggest their promising applications in chemical sensing.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 6