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On the capacity of liquid-liquid interfaces

Title
On the capacity of liquid-liquid interfaces
Type
Article in International Scientific Journal
Year
1997
Authors
Pereira, CM
(Author)
FCUP
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Schmickler, W
(Author)
Other
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Silva, AF
(Author)
FCUP
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Sousa, MJ
(Author)
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Journal
Vol. 268
Pages: 13-20
ISSN: 0009-2614
Publisher: Elsevier
Scientific classification
FOS: Natural sciences > Chemical sciences
Other information
Authenticus ID: P-001-BMS
Abstract (EN): The differential capacity of a large number of liquid-liquid interfaces has been determined by impedance spectroscopy. Even in the absence of ion pairing, the interfacial capacity was always larger than predicted by Gouy-Chapman theory. These findings are explained within a simple model, in which an extended mixed-boundary layer exists at the interface, whose thickness extends over several solvent diameters.
Language: English
Type (Professor's evaluation): Scientific
No. of pages: 8
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