Tunning pore filling of anodic alumina templates by accurate control of the bottom barrier layer thickness

• Type: Article in International Scientific Journal
• Date: 2011

Authors

sousa, c. t. (Author) Other; leitao, d. c. (Author) Other; proenca, m. p. (Author) FCUP; apolinario, a. (Author) Other; correia, j. g. (Author) Other; ventura, j. (Author) FCUP; araujo, j. p. (Author) FCUP

Journal

Title: Nanotechnology

Vol. 22

Final page: 315602

ISSN: 0957-4484

Publisher: Institute of Physics Publishing

Indexing

ISI Web of Knowledge - 66 Citations

Scopus - 67 Citations

Other information

Authenticus ID: P-002-NSZ

DOI: 10.1088/0957-4484/22/31/315602

Abstract (EN): The role of the alumina barrier layer thickness (delta(b)) on the growth of Ni nanowires (NWs) in porous anodic alumina (PAA) has been revealed. By varying the final anodization voltage to form dendrites at the bottom of the nanoporous structure, we are able to optimize delta(b) (in the 2-16 nm range), allowing us to obtain a Ni pore filling percentage (f(p)) of almost 100% for delta(b) = 10 nm. However, deviations from this optimal delta(b)-value led to a strong decrease of f(p). Moreover, an increase of the electrodeposition efficiency (EE) and NW homogeneity was also verified for delta(b) up to 10 nm. Such increase in nominal delta(b) leads to a consistent growth rate in all pores and consequently a complete and uniform nanopore filling. On the other hand, the decrease in electrodeposition efficiency visible for delta(b) > 10 nm is related with hydrogen evolution and dielectric breakdown of the insulator layer due to the required high deposition voltages. Non-uniform NW growth is then visible, with the consequent decrease in f(p). The control of the pore filling and length homogeneity of the fabricated 1D metallic nanostructures, combined with the ability to adjust the pore dimensions of PAA, can bring novel approaches for the fabrication of nano-objects and thus exciting new applications.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 6