Experimental and computational thermodynamic study of ortho- meta- and para-aminobenzamide

• Type: Article in International Scientific Journal
• Date: 2013

Authors

Ana R R P Almeida (Author) Other; Manuel J S Monte (Author) FCUP; Agostinha A R Matos (Author) FCUP; Victor M F Morais (Author) ICBAS

Journal

Title: Journal of Chemical Thermodynamics

Vol. 59

Pages: 222-232

ISSN: 0021-9614

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 24 Citations

Scopus - 24 Citations

Scientific classification

FOS: Engineering and technology > Mechanical engineering

Other information

Authenticus ID: P-001-ZZ1

DOI: 10.1016/j.jct.2012.12.006

Abstract (EN): The vapour pressures of the three crystalline isomers of aminobenzamide were measured using the Knudsen mass-loss effusion technique. From the temperature dependence of the vapour pressures, the standard (p degrees = 0.1 MPa) molar enthalpies, Gibbs energies and entropies of sublimation, at T = 298.15 K, were derived. The standard molar enthalpies of formation of the three isomeric aminobenzamides in the crystalline phase, at T = 298.15 K, were determined from static bomb calorimetric experiments. These values were combined with the results of standard molar enthalpies of sublimation to derive the standard molar enthalpy of formation in gaseous phase, at T = 298.15 K, of ortho-aminobenzamide, -(113.1 +/- 1.5) kJ.mol(-1), meta-aminobenzamide, -(98.9 +/- 1.6) kJ.mol(-1), and para-aminobenzamide, -(100.3 +/- 1.6) kJ.mol(-1). The temperature and molar enthalpy of fusion of the studied compounds were measured using differential scanning calorimetry. Additionally, very high-level quantum-chemical calculations at the composite G3 level have been conducted in an attempt to accurately describing the energetic of all isomers. The experimentally observed enthalpies of formation have been fully corroborated by the very accurate calculations.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 11