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Synthesis of new beta-substituted meso-tetraphenylporphyrins via 1,3-dipolar cycloaddition reactions. 1

Title
Synthesis of new beta-substituted meso-tetraphenylporphyrins via 1,3-dipolar cycloaddition reactions. 1
Type
Article in International Scientific Journal
Year
2002
Authors
Silva, AMG
(Author)
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Tome, AC
(Author)
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Neves, MGPMS
(Author)
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Silva, AMS
(Author)
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Cavaleiro, JAS
(Author)
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Journal
Vol. 67
Pages: 726-732
ISSN: 0022-3263
Other information
Authenticus ID: P-000-QB1
Abstract (EN): The azomethine ylide generated from the reaction of (beta-formyl-meso-tetraphenylporphyrinato)nickel(II) with N-methylglycine reacts with a range of dipolarophiles, yielding new beta-substituted-meso-tetraphenylporphyrins.. The regio- and stereochemistry of the new compounds was established using one- and two-dimensional NMR techniques.
Language: English
Type (Professor's evaluation): Scientific
No. of pages: 7
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