Impact of gaseous interferents on palladium expansion for hydrogen optical sensing: A time stability study

• Type: Article in International Scientific Journal
• Date: 2024

Authors

Almeida, MAS (Author) Other; de Almeida, JMMM (Author) FCUP; Coelho, LCC (Author) FCUP

Journal

Title: Optics and Laser Technology

Vol. 170

ISSN: 0030-3992

Publisher: Elsevier

Indexing

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Other information

Authenticus ID: P-00Z-6ZR

DOI: 10.1016/j.optlastec.2023.110193

Abstract (EN): Continuous monitoring of hydrogen (H2) concentration is critical for safer use, which can be done using optical sensors. Palladium (Pd) is the most commonly used transducer material for this monitoring. This material absorbs H2 leading to an isotropic expansion. This process is reversible but is affected by the interaction with interferents, and the lifetime of Pd thin films is a recurring issue. Fiber Bragg Grating (FBG) sensors are used to follow the strain induced by H2 on Pd thin films. In this work, it is studied the stability of Pd-coated FBGs, protected with a thin Polytetrafluoroethylene (PTFE) layer, 10 years after their deposition to assess their viability to be used as H2 sensors for long periods of time. It was found that Pd coatings that were PTFE-protected after deposition had a longer lifetime than unprotected films, with the same sensitivities that they had immediately after their deposition, namely 23 and 10 pm/vol% for the sensors with 150 and 100 nm of Pd, respectively, and a saturation point around 2 kPa. Furthermore, the Pd expansion was analyzed in the presence of H2, nitrogen (N2), carbon dioxide (CO2), methane (CH4) and water vapor (H2O), finding that H2O is the main interferent. Finally, an exhaustive test for 90 h is also done to analyze the long-term stability of Pd films in dry and humid environments, with only the protected sensor maintaining the long-term response. As a result, this study emphasizes the importance of using protective polymeric layers in Pd films to achieve the five-year lifetime required for a real H2 monitoring application.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 10