Homogeneous and heterogenised new gold C-scorpionate complexes as catalysts for cyclohexane oxidation

• Type: Article in International Scientific Journal
• Date: 2013

Authors

M. Peixoto de Almeida (Author) FEUP; L.M.D.R.S. Martins (Author) Other; S.A.C. Carabineiro (Author) FEUP; T. Lauterbach (Author) Other; F. Rominger (Author) Other; A.S.K. Hashmi (Author) Other; A.J.L. Pombeiro (Author) Other; J.L. Figueiredo (Author) FEUP

Journal

Title: Catalysis Science and Technology

Vol. 3

Pages: 3056-3069

ISSN: 2044-4753

Publisher: Royal Society of Chemistry

Indexing

ISI Web of Knowledge - 91 Citations

ISI Web of Science

Scopus - 96 Citations

Scientific classification

FOS: Engineering and technology > Chemical engineering

CORDIS: Technological sciences > Engineering > Chemical engineering

Other information

Authenticus ID: P-006-FF6

DOI: 10.1039/c3cy00552f

Abstract (EN): Gold(III) complexes of type [AuCl2{eta(2)-RC(R'pz)(3)}]Cl [R = R' = H (1), R = CH2OH, R' = H (2) and R = H, R' = 3,5-Me-2(3), pz = pyrazol-1-yl] were supported on carbon materials (activated carbon, carbon xerogel and carbon nanotubes) and used for the oxidation of cyclohexane to cyclohexanol and cyclohexanone, with aqueous H2O2, under mild conditions.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 14