Experimental determination, correlation, and prediction of physical properties of the ternary mixtures ethanol and 1-propanol + water + 1-ethyl-3-methylpyridinium ethylsulfate at 298.15 K

• Type: Article in International Scientific Journal
• Date: 2009

Authors

Noélia Calvar (Author) FEUP; Elena Gómez (Author) FEUP; Begoña González (Author) FEUP; Ángeles Domínguez (Author) Other

Journal

Title: Journal of Chemical & Engineering Data

Vol. 54

Pages: 2229-2234

ISSN: 0021-9568

Publisher: American Chemical Society

Indexing

ISI Web of Science

Scopus - 3 Citations

COMPENDEX

Scientific classification

FOS: Engineering and technology

CORDIS: Technological sciences

Other information

Authenticus ID: P-008-PBY

DOI: 10.1021/je8009732

Abstract (EN): In this work, densities, ¿, refractive indices, nD, and dynamic viscosities, ¿, of the ternary mixtures of the alcohols ethanol and 1-propanol + water with 1-ethyl-3-methylpyridinium ethylsulfate [empy][eSO 4] have been measured at T ) 298.15 K and atmospheric pressure. Excess molar volumes, VE, refractive index deviations, ¿n D, and viscosity deviations, ¿¿, have been calculated from experimental data and fitted to various correlation equations, obtaining good results. The excess properties have been used to test several prediction models, finding out that symmetric models give lower deviations than asymmetric models. © 2009 American Chemical Society.

Language: English

Type (Professor's evaluation): Scientific