Resumo (PT):
Abstract (EN):
A detailed kinetic model for the flowing nitrogen microwave discharge and post-discharge is developed with the aim of gaining a deeper understanding into the processes responsible for the formation of the short-lived afterglow of nitrogen and for the enhancement of the concentration of metastable, measured at approximately the same position in Sadeghi et al (2001 J. Phys. D: Appl. Phys. 34 1779). The present work shows that the peaks observed in the afterglow, for the density of molecules in radiative N2(B 3Πg) and and metastable states, can be explained as a result of a pumping-up phenomenon into the vibrational ladder produced by near-resonant V–V energy-exchange collisions, involving vibrationally excited molecules in levels as high as v ∼ 35. The present predictions are shown to be in good agreement with the measured concentrations for metastables and N(4S) atoms, and with the emission intensities of 1+ and 1− system bands of N2.
Language:
Portuguese
Type (Professor's evaluation):
Scientific
No. of pages:
11