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Self-consistent Kinetic Model of a Flowing Nitrogen Afterglow

Title
Self-consistent Kinetic Model of a Flowing Nitrogen Afterglow
Type
Article in International Scientific Journal
Year
2004
Authors
Paulo Araújo Sá
(Author)
FEUP
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V. Guerra
(Author)
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J. Loureiro
(Author)
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N. Sadeghi
(Author)
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Journal
Vol. 37 No. 2
Pages: 221-231
ISSN: 0022-3727
Scientific classification
FOS: Natural sciences
Other information
Resumo (PT):
Abstract (EN): A detailed kinetic model for the flowing nitrogen microwave discharge and post-discharge is developed with the aim of gaining a deeper understanding into the processes responsible for the formation of the short-lived afterglow of nitrogen and for the enhancement of the concentration of metastable, measured at approximately the same position in Sadeghi et al (2001 J. Phys. D: Appl. Phys. 34 1779). The present work shows that the peaks observed in the afterglow, for the density of molecules in radiative N2(B 3Πg) and and metastable states, can be explained as a result of a pumping-up phenomenon into the vibrational ladder produced by near-resonant V–V energy-exchange collisions, involving vibrationally excited molecules in levels as high as v ∼ 35. The present predictions are shown to be in good agreement with the measured concentrations for metastables and N(4S) atoms, and with the emission intensities of 1+ and 1− system bands of N2.
Language: Portuguese
Type (Professor's evaluation): Scientific
No. of pages: 11
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