Ancient Portuguese Ceramic Wall Tiles ("Azulejos"): Characterization of the Glaze and Ceramic Pigments

• Type: Article in International Scientific Journal
• Date: 2009

Authors

Pereira, M (Author) Other; de Lacerda Aroso, T (Author) Other; Gomes, MJM (Author) Other; Mata, A (Author) Other; Alves, LC (Author) Other; Colomban, P (Author) Other

Journal

Title: Journal of Nano Research

Vol. 8

Pages: 79-88

ISSN: 1662-5250

Publisher: Trans Tech Publications Ltd

Indexing

ISI Web of Knowledge - 31 Citations

Scopus - 39 Citations

Other information

Authenticus ID: P-003-R23

DOI: 10.4028/www.scientific.net/jnanor.8.79

Abstract (EN): Ancient ceramic wall tiles, called "azulejo", firstly used on Portuguese churches, monasteries and palaces (15-18(th) century) have progressively been used in particular houses till the last century. These tiles and its use in huge decorative panels can be considered as a precious but fragile cultural heritage from Brazil to India, in several countries influenced by Portuguese culture. Morphologically, these tiles are composed by a porous clay-based ceramic body, the terracotta, covered by a protective glassy phase, the glaze. As artistic paintings, these murals incorporated various kinds of pigments in the glaze layer to create a pictorial impact on the walls of rich palaces or churches, real and durable monumental works-of-art. In the 21(st) century, degradation marks are visible on these ceramic tiles because of their use under corrosive conditions (moisture, atmospheric cycles ... ) along centuries. In order to promote their conservation and enhance their restoration, the physical-chemical characterization of the azulejos is performed in the present work, using mainly non-destructive processes like micro-Raman spectroscopy or X-Ray diffraction. In particular, Raman spectroscopy allows the detection of some nano/microcrystals present in the amorphous glaze due to pigments or opacifying agents or related to the elaboration process of the azulejo. Based on the observation of various selected fragments, one states that very few pigments have been used as colouring agents in this ceramic art during 17-18(th) centuries. Thus, the relationship between the different colours, the introduced pigments and the structural aspects of the glass will be focused. Some features related with the ancient ceramic technology will also be discussed.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 10