Selective formic acid dehydrogenation at low temperature over a RuO2/COF pre-catalyst synthesized on the gram scale

• Type: Article in International Scientific Journal
• Date: 2020

Authors

Liliana P. L. Gonçalves (Author) Other; David B. Christensen (Author) Other; Maria Meledina (Author) Other; Laura M. Salonen (Author) Other; Dmitri Y. Petrovykh (Author) Other; Enrique Carbó-Argibay (Author) Other; Juliana P. S. Sousa (Author) Other; Olívia S. G. P. Soares (Author) FEUP; Manuel Fernando R. Pereira (Author) Other; Søren Kegnæs (Author) Other; Yuri V. Kolen'ko (Author) Other

Journal

Title: Catalysis Science and Technology

Vol. 10

Pages: 1991-1995

ISSN: 2044-4753

Publisher: Royal Society of Chemistry

Indexing

ISI Web of Knowledge - 0 Citations

Scopus - 6 Citations

Other information

Authenticus ID: P-00S-00F

DOI: 10.1039/d0cy00145g

Abstract (EN): A pre-catalyst, consisting of RuO2 nanoparticles and clusters anchored on TpBD-Me-2 COF, was synthesized. During catalytic formic acid dehydrogenation, RuO2 undergoes in situ reduction to metallic Ru, forming an active and selective catalyst, which outperforms the commercial Ru-C catalyst. The chemical structure of the COF supporting material is maintained during stability testing.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 5