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HPLC with carbohydrate carbamate chiral phases: Influence of chiral phase structure on enantioselectivity

Title
HPLC with carbohydrate carbamate chiral phases: Influence of chiral phase structure on enantioselectivity
Type
Article in International Conference Proceedings Book
Year
1994
Authors
Matlin, SA
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Tiritan M.E.
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Crawford, AJ
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Cass, QB
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Boyd, DR
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Conference proceedings International
Pages: 135-140
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Authenticus ID: P-009-14Y
Abstract (EN): The enantioselective resolution of trans-stilbene oxide and of 23 chiral sulfoxides was investigated on cellulose and amylose tris(arylcarbamate) stationary phases coated on aminopropylated 7 ¿m spherical silica with 500 Å diameter pores. Cellulose tris-(3,5 dimethylphenylcarbamate) showed good resolving power for many of the sulfoxides and amylose tris-(3,5 dimethoxyphenylcarbamate) showed advantages for the resolution of certain sulfoxides which were not separated on other phases.
Language: English
Type (Professor's evaluation): Scientific
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