The influence of the halogen atoms and acetyl group on vapour pressures and related properties of the p-haloacetophenones

• Type: Article in International Scientific Journal
• Date: 2016

Authors

Almeida, ARRP (Author) FCUP; Manuel J S Monte (Author) FCUP

Journal

Title: Journal of Chemical Thermodynamics

Vol. 92

Pages: 118-125

ISSN: 0021-9614

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 15 Citations

Scopus - 15 Citations

Other information

Authenticus ID: P-00G-NP3

DOI: 10.1016/j.jct.2015.09.004

Abstract (EN): This work reports experimental vapour pressures at different temperatures of four halogenated acetophenones. The liquid phase vapour pressures of p-fluoro and p-chloro acetophenones were measured, respectively, across the temperatures ranges (255.1 to 310.2) K and (271.6 to 335.0) K, using a static method based on capacitance diaphragm manometers. This experimental technique was also used to measure the vapour pressures of both (crystalline and liquid) condensed phases of p-bromo-and p-iodoacetophenones, respectively, through the temperature intervals (295.3 to 378.4) K and (313.1 to 402.0) K. The temperatures and molar enthalpies and entropies of fusion of the four p-halogenated acetophenones were determined using differential scanning calorimetry. The standard molar enthalpies, entropies and Gibbs energies of sublimation and of vaporisation, at selected reference temperatures, were derived from the experimental results. The contributions of the acetyl group and of the constituent halogen atoms to these thermodynamic properties were also predicted through correlation equations.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 8