FLOW-INJECTION ANALYSIS OF HIGH CHLORIDE LEVELS IN ELECTROPLATING BATHS USING ONLINE DIALYSIS AND POTENTIOMETRIC DETECTION

• Type: Article in International Scientific Journal
• Date: 1995

Authors

ARAUJO, AN (Author) FFUP; ETXEBARRIA, MB (Author) Other; LIMA, JLFC (Author) FFUP; MONTENEGRO, MCBSM (Author) FFUP; OLMOS, RP (Author) Other

Journal

Title: Analytical and Bioanalytical Chemistry

Vol. 351

Pages: 614-617

ISSN: 1618-2642

Publisher: Springer Nature

Indexing

ISI Web of Knowledge - 15 Citations

Scopus - 14 Citations

Scientific classification

FOS: Natural sciences > Chemical sciences

Other information

Authenticus ID: P-001-H34

DOI: 10.1007/bf00323335

Abstract (EN): A method for the flow injection analysis (FIA) of high concentrations of chloride in electroplating baths using potentiometric detection is proposed. The system includes a unit of dialysis to promote dilution of samples and a tubular electrode with an homogeneous crystalline membrane as detector. The system was optimized in order to analyse samples within a broad range of concentrations and at high levels of chloride, thereby making pretreatment of the samples unnecessary. It results in a simple manifold applicable over the 4.0 x 10(-2) and 3.0 mol L(-1) range with a throughput of about 30 samples/h. Seven different plating bath samples were analysed by the proposed method and the quality of the results compared with those obtained by the conventional procedure. Satisfactory agreement was observed.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 4