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A generalised Phan-Thien-Tanner model

Title
A generalised Phan-Thien-Tanner model
Type
Article in International Scientific Journal
Year
2019
Authors
L. L. Ferrás
(Author)
Other
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M. L. Morgado
(Author)
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M. Rebelo
(Author)
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Gareth H. McKinley
(Author)
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A. M. Afonso
(Author)
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Journal
Vol. 269
Pages: 88-99
ISSN: 0377-0257
Publisher: Elsevier
Other information
Authenticus ID: P-00Q-S44
Abstract (EN): In this work we propose a novel generalised form of the Phan¿Thien and Tanner (PTT) model by considering a new functional form of the nonlinear expression characterizing the destruction of physical network junctions and entanglements. This new function of the trace of the stress tensor is given by the generalized Mittag¿Leffler function, and contains the familiar exponential form of the original Phan¿Thien and Tanner model as a limiting case, but affords additional fitting flexibility through the inclusion of one or two additional fitting constants. We perform fits to experimental data in shear and extension and show that this generalized expression allows a better description of the rheological responses for a range of complex materials such as polymer melts and semidilute polymer solutions. By using an appropriate information criterion, we also demonstrate that the resulting generelized model remains parsimonious but provides improved fits of real world data. © 2019 The Authors
Language: English
Type (Professor's evaluation): Scientific
No. of pages: 12
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