Resumo (PT):
Abstract (EN):
Nanostructured titanium materials with high UV-visible activity were synthesized in the
collaborative project Clean Water FP7. In this study, the efficiency of some of these catalysts
to degrade endocrine disruptor compounds, using bisphenol A as the model compound,
was evaluated. Titanium dioxide P25 (AEROXIDE TiO2, Evonik Degussa) was used
as the reference. The photocatalytic degradation was carried out under the UV part of a
simulated solar light (280e400 nm) and under the full spectrum of a simulated solar light
(200 nm-30 mm). Catalytic efficiency was assessed using several indicators such as the
conversion yield, the mineralization yield, by-product formation and the endocrine
disruption effect of by-products. The new synthesized catalysts exhibited a significant
degradation of bisphenol A, with the so-called ECT-1023t being the most efficient. The
intermediates formed during photocatalytic degradation experiments with ECT-1023t as
catalyst were monitored and identified. The estrogenic effect of the intermediates was also
evaluated in vivo using a ChgH-GFP transgenic medaka line. The results obtained show that
the formation of intermediates is related to the nature of the catalyst and depends on the
experimental conditions. Moreover, under simulated UV, in contrast with the results obtained
using P25, the by-products formed with ECT-1023t as catalyst do not present an
estrogenic effect.
Idioma:
Inglês
Tipo (Avaliação Docente):
Científica
Nº de páginas:
9