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A new approach for the estimation of sublimation enthalpies and vapor pressures of crystalline benzene derivatives

Title
A new approach for the estimation of sublimation enthalpies and vapor pressures of crystalline benzene derivatives
Type
Article in International Scientific Journal
Year
2013
Authors
Manuel J S Monte
(Author)
FCUP
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Ana R R P Almeida
(Author)
Other
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Journal
Title: Structural ChemistryImported from Authenticus Search for Journal Publications
Vol. 24
Pages: 2001-2016
ISSN: 1040-0400
Publisher: Springer Nature
Scientific classification
FOS: Natural sciences > Chemical sciences
Other information
Authenticus ID: P-006-JBD
Abstract (EN): This work presents a new approach for estimating sublimation enthalpies and vapor pressures of substituted benzenes. Proposed estimating equations were based on a collection of selected literature results of vapor pressures of ca. 240 benzene derivatives attached with 30 different substituents. Compared to experimental results, best estimates are obtained from the equations that include the temperature of fusion. A review of the results determined for substituted benzenes using two different calorimetric techniques shows that the results of enthalpies of sublimation derived from vapor pressures seem to be more reliable than those derived from the calorimetric techniques.
Language: English
Type (Professor's evaluation): Scientific
Contact: mjmonte@fc.up.pt
No. of pages: 16
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