Effect of CO and CO 2 on H 2 permeation through finger-like Pd-Ag membranes

• Type: Article in International Scientific Journal
• Date: 2012

Authors

C. V. Miguel (Author) FEUP; A. Mendes (Author) FEUP; S. Tosti (Author) Other; Luís M. Madeira (Author) FEUP

Journal

Title: International Journal of Hydrogen Energy

Vol. 37 No. 17

ISSN: 0360-3199

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 25 Citations

ISI Web of Science

Scopus - 46 Citations

INSPEC

Scientific classification

FOS: Engineering and technology > Chemical engineering

Associated Projects

PTDC/EQU-ERQ/098730/2008 - Integração de Reactores de Membrana com Processos Adsorptivos usando-se Catalisadores Suportados em Monolitos para a Produção de Hidrogénio de Elevada Pureza

Other information

Authenticus ID: P-002-64K

DOI: 10.1016/j.ijhydene.2012.05.131

Abstract (EN): The permeance of a 50 mm thick PdAg (25 wt.% of silver) tubular membrane towards hydrogen was evaluated for hydrogen feed streams or binary mixtures of industrial relevance, namely of H2/CO or H2/CO2. It was proposed a rearrangement of the SievertseLangmuir (SL) equation to account for the inhibition effect on the membrane permeance towards H2 due to the presence of CO or CO2. Such modification is based on the average partial pressure of CO or CO2 and the logarithm-mean driving-force to account for concentration gradients along the axial length of the tubular membrane. Comparison with the original SL equation evidenced relative deviations < 10.7%. The experimental data showed good agreement with the SL model. It was found that carbon monoxide has a much stronger inhibition effect on hydrogen permeation than carbon dioxide. Considering the values obtained for the adsorption enthalpy of each gas, it was concluded that both CO and CO2 adsorb physically on the membrane surface.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 8