Temperature and solid properties effects on gas-liquid mass transfer

• Type: Article in International Scientific Journal
• Date: 2010

Authors

Ferreira, A (Author) FEUP; Cecilia Ferreira (Author) FEUP; Teixeira, JA (Author) Other; Rocha, F (Author) FEUP

Journal

Title: Chemical Engineering Journal

Vol. 162

Pages: 743-752

ISSN: 1385-8947

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 34 Citations

ISI Web of Science

Scopus - 50 Citations

INSPEC

COMPENDEX

Scientific classification

CORDIS: Technological sciences > Engineering > Chemical engineering

FOS: Engineering and technology > Chemical engineering

Other information

Authenticus ID: P-003-3ZK

DOI: 10.1016/j.cej.2010.05.064

Abstract (EN): The knowledge about the effect of solid phase properties, at different temperatures, on gas-liquid transfer and the respective physical mechanisms has been poorly studied. In the present work, the temperature and solid properties (size and density) effects on the gas-liquid mass transfer characteristics in a bubble column were experimentally evaluated. Gas-liquid-solid systems formed by air/water/polyvinyl chloride (PVC) beads and air/water/expandable polystyrene (EPS) beads were used. For each system, volumetric liquid side mass transfer coefficient, k(L)a, was determined under different temperatures (20-35 degrees C), superficial gas velocities (up to 7.2 mm/s), solids sizes (210, 549 and 591 mu m) and concentration (up to 5 vol.%). The results show that the temperature plays an important role on mass transfer phenomena as k(L)a increases as temperature is increased. However, temperature does not have, significantly, influence on the solids effect on k(L)a. In what concerns the effect of the solids on k(L)a, a negative effect of their presence is observed being this effect more pronounced for the largest particles (for PVC). In addition, for the same solid size, a decrease in k(L)a occurs when the solid loading increases (observed in both cases, PVC and EPS). Complementary, bubble/particle interaction studies, using an image analysis technique, were also done aiming a better understanding of the effects of the two types of particles - PVC and EPS - on k(L)a values, being clearly confirmed that physical (e.g. density) and chemical properties of the solids are important parameters to be taken into account on mass transfer and hydrodynamic studies. Based on theoretical models for k(L) and a, an empirical correlation for k(L)a dependence on the experimental variables was developed. The experimental results were fitted with a mean deviation of 5%, that is similar to the experimental error (5%).

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 10