Electrochemistry of 2,8-dithia[9],(2,9)-1,10-phenanthrolinophane (L) at the polarized water/1, 2-dichloroethane interface: Evaluation of the complexation properties towards transition and post-transition metal ions

• Type: Article in International Scientific Journal
• Date: 2006

Authors

Ferreira, ES (Author) Other; Garau, A (Author) Other; Lippolis, V (Author) Other; Pereira, CM (Author) FCUP; Silva, F (Author) FCUP

Journal

The Journal is awaiting validation by the Administrative Services.

Title: JOURNAL OF ELECTROANALYTICAL CHEMISTRY

Vol. 587

Pages: 155-160

ISSN: 0022-0728

Indexing

ISI Web of Knowledge - 28 Citations

Scopus - 27 Citations

Scientific classification

FOS: Natural sciences > Chemical sciences

Other information

Authenticus ID: P-004-NFX

DOI: 10.1016/j.jelechem.2005.11.005

Abstract (EN): The coordination chemistry of 2,8-dithia[9],(2,9)-1,10-phenanthrolinophane (L) towards transition and post-transition metal ions such as Cu(II), Cu(I), Cd(II), Co(II), Ni(II), Pb(II) and Zn(II) was studied at the polarized water/1,2-dichloroethane interface by cyclic voltammetry. The dependence of the half-wave transfer potential on the ligand and metal concentrations was used to formulate the stoichiometry, and to evaluate the association constants of the complexes formed between L and Pb(II).

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 6