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ENTHALPIES OF COMBUSTION, VAPOR-PRESSURES, AND ENTHALPIES OF SUBLIMATION OF 2-CYANOQUINOLINE AND 3-CYANOQUINOLINE

Title
ENTHALPIES OF COMBUSTION, VAPOR-PRESSURES, AND ENTHALPIES OF SUBLIMATION OF 2-CYANOQUINOLINE AND 3-CYANOQUINOLINE
Type
Article in International Scientific Journal
Year
1995
Authors
MATOS, MAR
(Author)
FCUP
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AMARAL, LMPF
(Author)
Other
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Journal
Vol. 27
Pages: 1187-1196
ISSN: 0021-9614
Publisher: Elsevier
Scientific classification
FOS: Engineering and technology > Mechanical engineering
Other information
Authenticus ID: P-001-G2S
Abstract (EN): The standard (p degrees = 0.1 MPa) molar enthalpies of formation for crystalline 2-cyanoquinoline, 2-CN-C9H6N, and 3-cyanoquinoline, 3-CN-C9H6N, were derived from the standard molar enthalpies of combustion, in oxygen, at the temperature T = 298.15 K, measured by static bomb-combustion calorimetry; the Knudsen mass-loss effusion technique was used to measure the vapour pressures of the crystals as functions of temperature, and the standard molar enthalpies of sublimation, at T = 298.15 K, were derived by the Clausius-Clapeyron equation. Direct measurements of the standard molar enthalpies of sublimation, using microcalorimetry, for 2-cyanoquinoline and 3-cyanoquinoline confirmed the values from the Knudsen technique. [GRAPHICS] (c) 1995 Academic Press Limited
Language: English
Type (Professor's evaluation): Scientific
No. of pages: 10
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