Enthalpies of combustion, vapour pressures, and enthalpies of sublimation of 2-phenylquinoline and 2,2'-biquinoline

• Type: Article in International Scientific Journal
• Date: 1997

Authors

daSilva, MAVR (Author) FCUP; Matos, MAR (Author) FCUP; Amaral, LMPF (Author) Other

Journal

Title: Journal of Chemical Thermodynamics

Vol. 29

Pages: 1129-1136

ISSN: 0021-9614

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 14 Citations

Scopus - 13 Citations

Scientific classification

FOS: Engineering and technology > Mechanical engineering

Other information

Authenticus ID: P-001-AKJ

Abstract (EN): The standard (p(o) = 0.1 MPa) molar enthalpies of formation for crystalline 2-phenylquinoline and 2,2'-biquinoline were derived from the standard molar enthalpies of combustion, in oxygen, at the temperature T = 298.15 K, measured by static bomb combustion calorimetry; the Knudsen mass-loss effusion technique was used to measure the vapour pressures of the crystals as functions of temperature, and the standard molar enthalpies of sublimation, at T = 298.15 K, were derived using the Clausius-Clapeyron equation. [GRAPHICS] (C) 1997 Academic Press Limited.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 8