Thermochemical studies of 1-hydroxyisoquinoline, 5-hydroxylsoquinoline and 1,5-dihydroxyisoquinoline

• Type: Article in International Scientific Journal
• Date: 2005

Authors

da Silva, MAVR (Author) FCUP; Matos, MAR (Author) FCUP; Amaral, LMF (Author) Other

Journal

Title: Journal of Chemical Thermodynamics

Vol. 37

Pages: 1312-1317

ISSN: 0021-9614

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 7 Citations

Scopus - 7 Citations

Scientific classification

FOS: Engineering and technology > Mechanical engineering

Other information

Authenticus ID: P-000-094

DOI: 10.1016/j.jct.2005.03.009

Abstract (EN): The standard (p degrees = 0. 1 MPa) molar enthalpies of formation, Delta(f)H degrees(m), for crystalline 1 -hydroxyisoquinoline, 5-hydroxyisoquinoline and 1,5-diidroxyisoquinoline, were derived from the standard molar enthalpies of combustion, in oxygen, at the temperature 298.15 K, measured by static bomb-combustion calorimetry. The standard molar enthalpies of sublimation, Delta(cr)(g)H degrees(m), at T = 298.15 K, were determined by Calvet microcalorimetry. The results were as follows: [GRAPHICS] The derived standard molar enthalpies of formation, in the gaseous state, are analysed in terms of enthalpic increments and interpreted in terms of molecular structure.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 6