Standard molar enthalpies of formation of 2-chloroquinoline, 4-chloroquinoline, 6-chloroquinoline and 4,7-dichloroquinoline by rotating-bomb calorimetry

• Type: Article in International Scientific Journal
• Date: 2006

Authors

da Silva, MAVR (Author) FCUP; Matos, MAR (Author) FCUP; Amaral, LMPF (Author) Other

Journal

Title: Journal of Chemical Thermodynamics

Vol. 38

Pages: 49-55

ISSN: 0021-9614

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 5 Citations

Scopus - 0 Citations

Scientific classification

FOS: Engineering and technology > Mechanical engineering

Other information

Authenticus ID: P-004-Q2P

DOI: 10.1016/j.jct.2005.03.011

Abstract (EN): The standard (p(o) = 0.1 MPa) molar enthalpies of combustion, Delta(c)H(m)(o), for crystalline 2-, 4-, 6-chloroquinoline and 4.7-dichloroniquinoline were determined at the temperature 298.15 K using a rotating-bomb combustion calorimeter. The standard molar enthalpies of sublimation, Delta(cr)(g)H(m)(o) at T = 298.15 K, were determined by Calvet microcalorimetry. The results were as follows: [GRAPHICS] These values were used to derive the standard molar enthalpies of formation of the compounds in their crystalline and gaseous phases, respectively. The derived standard molar enthalpies of formation, in the gaseous state, are analysed in terms of enthalpic increments and interpreted in terms of molecular structure.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 7