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Thermochemical properties of two benzimidazole derivatives: 2-phenyl- and 2-benzylbenzimidazole

Title
Thermochemical properties of two benzimidazole derivatives: 2-phenyl- and 2-benzylbenzimidazole
Type
Article in International Scientific Journal
Year
2005
Authors
da Silva, MDDMCR
(Author)
FCUP
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Amaral, LMPF
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Elguero, J
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Jimenez, P
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Roux, MV
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Davalos, JZ
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Temprado, M
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Cabildo, P
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Claramunt, RM
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Mo, O
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Yanez, M
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Journal
Vol. 37
Pages: 1168-1176
ISSN: 0021-9614
Publisher: Elsevier
Scientific classification
FOS: Engineering and technology > Mechanical engineering
Other information
Authenticus ID: P-000-0QD
Abstract (EN): The standard (p degrees = 0.1 MPa) molar enthalpy of formation for gaseous 2-phenylbenzimidazole (2-PhBIM) and 2-benzylbenzimidazole (2-BzBIM) were derived from the standard molar enthalpies of combustion, at T = 298.15 K, measured by static bomb calorimetry, and the standard molar enthalpy of sublimation, at T = 298.15 K, measured by Calvet microcalorimetry in the case of 2-phenylbenzimidazole or derived from the variation of the vapour pressures, determined by the Knudsen effusion technique, with temperatures between (393 and 412) K for 2-benzylbenzimidazole. Heat capacities, in the temperature ranges from (268.15 to 322.10) K for 2-phenylbenzimidazole and (270.15 to 316.02) K for 2-benzylbenzimidazole, were also measured with a differential scanning calorimeter.
Language: English
Type (Professor's evaluation): Scientific
Contact: risilva@fc.up.pt
No. of pages: 9
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