Go to:
Logótipo
Comuta visibilidade da coluna esquerda
Você está em: Start > Publications > View > New insights into the structure and properties of electroactive polymer films derived from [Ni(salen)]
Publication

Publications

New insights into the structure and properties of electroactive polymer films derived from [Ni(salen)]

Title
New insights into the structure and properties of electroactive polymer films derived from [Ni(salen)]
Type
Article in International Scientific Journal
Year
1997
Authors
VilasBoas, M
(Author)
Other
The person does not belong to the institution. The person does not belong to the institution. The person does not belong to the institution. Without AUTHENTICUS Without ORCID
deCastro, B
(Author)
FCUP
View Personal Page You do not have permissions to view the institutional email. Search for Participant Publications View Authenticus page Without ORCID
Christensen, PA
(Author)
Other
The person does not belong to the institution. The person does not belong to the institution. The person does not belong to the institution. Without AUTHENTICUS Without ORCID
Hillman, AR
(Author)
Other
The person does not belong to the institution. The person does not belong to the institution. The person does not belong to the institution. Without AUTHENTICUS Without ORCID
Journal
Title: Inorganic ChemistryImported from Authenticus Search for Journal Publications
Vol. 36
Pages: 4919-4929
ISSN: 0020-1669
Scientific classification
FOS: Natural sciences > Chemical sciences
Other information
Authenticus ID: P-001-AEX
Abstract (EN): Oxidative electrochemical polymerization of (N,N'-ethylenebis(salicylideneaminato)) nickel(II), [Ni(salen)li in acetonitrile/TEAP was reinvestigated. The polymers were characterized by in situ FTIR and UV-visible spectroscopies in order to explore film structure and to clarify the electronic states as a function of the electrochemically controlled applied redox potential; oxidized species involved in polymerization and oxidative switching of the polymer were also assessed by en situ EPR experiments. Integration of data from all techniques revealed that (a) electropolymerization of [Ni(salen)] is ultimately a Ligand-based-process that takes place through a mixture of o- and p-linking of the phenyl rings and (b) poly[Ni(salen)] exhibits physical/chemical properties that cannot be attributed to an aggregation of individual complexes, behaving rather like a polyphenylene compound, with the metal ion acting as a bridge between biphenylene moieties.
Language: English
Type (Professor's evaluation): Scientific
No. of pages: 11
Documents
We could not find any documents associated to the publication.
Related Publications

Of the same journal

Three-Dimensional (3D) Microporous Iron Silicate with an Imandrite Type of Structure (2021)
Article in International Scientific Journal
Ferdov, S; Lopes, AML; araujo, j. p.; Shivachev, B; Titorenkova, R; Petrova, N; Nikolova, R
The Sulfur Shift: An Activation Mechanism for Periplasmic Nitrate Reductase and Formate Dehydrogenase (2013)
Article in International Scientific Journal
Nuno M F S A Cerqueira; Pedro A Fernandes; Pablo J Gonzalez; Jose J G Moura; Maria J Ramos
Synthesis, structure and magnetic behavior of five-coordinate bis(iminopyrrolyl) complexes of cobalt(II) containing PMe3 and THF ligands (2008)
Article in International Scientific Journal
Sonia A Carabineiro; Ronan M Bellabarba; Pedro T Gomes; Sofia I Pascu; Luis F Veiros; Cristina Freire; Laura C J Pereira; Rui T Henriques; Conceicao C Oliveira; John E Warren
Synthesis, Structure, and Catalytic Performance in Cyclooctene Epoxidation of a Molybdenum Oxide/Bipyridine Hybrid Material: {[MoO(3)(bipy)][MoO(3)(H(2)O)]}n (2010)
Article in International Scientific Journal
Marta Abrantes; Tatiana R. Amarante; Margarida M. Antunes; Sandra Gago; Filipe A. Almeida Paz ; Irene Margiolaki; Alírio E. Rodrigues; Martyn Pillinger ; Anabela A. Valente ; Isabel S. Gonçalves

See all (17)

Recommend this page Top
Copyright 1996-2025 © Faculdade de Direito da Universidade do Porto  I Terms and Conditions  I Acessibility  I Index A-Z
Page created on: 2025-08-07 at 20:56:56 | Privacy Policy | Personal Data Protection Policy | Whistleblowing