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Você está em: Start > Publications > View > (1,4-dioxane-O)(3,3 ',5,5 '-tetrachloro-2,2 '-[4-methyl-4-azaheptane-1,7-diyl-bis(nitrilomethylidyne-N)] diphenolato-O,O ')nickel(II), [Ni(3,5-Cl(4)salMetrien)]
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(1,4-dioxane-O)(3,3 ',5,5 '-tetrachloro-2,2 '-[4-methyl-4-azaheptane-1,7-diyl-bis(nitrilomethylidyne-N)] diphenolato-O,O ')nickel(II), [Ni(3,5-Cl(4)salMetrien)]

Title
(1,4-dioxane-O)(3,3 ',5,5 '-tetrachloro-2,2 '-[4-methyl-4-azaheptane-1,7-diyl-bis(nitrilomethylidyne-N)] diphenolato-O,O ')nickel(II), [Ni(3,5-Cl(4)salMetrien)]
Type
Article in International Scientific Journal
Year
1999
Authors
Gomes, L
(Author)
Other
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Pinho, D
(Author)
Other
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Freire, C
(Author)
FCUP
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de Castro, B
(Author)
FCUP
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Journal
Vol. 55
Pages: 1425-1427
ISSN: 0108-2701
Publisher: Blackwell
Scientific classification
FOS: Natural sciences > Chemical sciences
Other information
Authenticus ID: P-001-3AE
Abstract (EN): In the title compound, [Ni(C21H21Cl4N3O2)(C4H8O2)], the Ni atom has a distorted octahedral coordination geometry in which the pentadentate Schiff base ligand acts as an N3O2 donor and a molecule of 1,4-dioxane occupies the remaining coordination position. The N atoms adopt a meridional arrangement, coplanar with the O-donor atom of the dioxane molecule, and the ligand O atoms are trans-related. This conformation results in an approximate square-pyramidal coordination for the pentadentate ligand, with the dioxane molecule trans to the amine N atom.
Language: English
Type (Professor's evaluation): Scientific
No. of pages: 3
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