Visible-light-driven photocatalytic degradation of organic dyes using a TiO2 and waste-based carbon dots nanocomposite

• Type: Article in International Scientific Journal
• Date: 2025

Authors

Sendao, RMS (Author) Other; Algarra, M (Author) Other; Lázaro-Martínez, J (Author) Other; Brandao, ATSC (Author) Other; Gil, A (Author) Other; Carlos M Pereira (Author) FCUP; Joaquim C G E Esteves da Silva (Author) FCUP; da Silva, LP (Author) FCUP

Journal

Title: Colloids and Surfaces A: Physicochemical and Engineering Aspects

Vol. 713

ISSN: 0927-7757

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 0 Citations

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Other information

Authenticus ID: P-018-1Q8

DOI: 10.1016/j.colsurfa.2025.136475

Abstract (EN): Herein we report a visible-light-active photocatalytic nanocomposite (NC50:50) prepared from carbon dots (CDs) and TiO2 nanoparticles, which was applied to the photodegradation of organic dyes in water. The CDs incorporated corn stover, a major agricultural waste, and were prepared via hydrothermal treatment. Using a visible- light irradiation source and the dye methylene blue as a representative of the organic dyes class, we observed that a 374 % enhancement of the catalytic performance was achieved by adding CDs relative to bare TiO2. This was possible due to increased visible-light absorption and better photonic efficiency. Tests using reactive species scavengers indicated that three active species (superoxide anion, hydroxyl radicals, and electrons) were responsible for the photodegradation process, differing from bare TiO2 in which only the hydroxyl radical has a relevant role. Photocatalytic degradation was also observed toward Rhodamine B, Orange II and Methyl Orange. Finally, we performed a life cycle assessment (LCA) study to assess and analyse the associated environmental impacts of NC50:50 compared with other alternatives, which revealed that NC50:50 is the alternative resulting in the least environmental impacts. In summary, NC50:50 could, under visible-light irradiation, efficiently remove different organic dyes while incorporating organic waste materials and reducing the impacts associated with their use. We expect that this study provides a base for a more environmentally sustainable design of visible- light-active photocatalysts via waste upcycling.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 15