Physical properties of pure 1-ethyl-3-methylimidazolium ethylsulfate and its binary mixtures with ethanol and water at several temperatures

• Type: Article in International Scientific Journal
• Date: 2006

Authors

Elena Gómez (Author) FEUP; Begoña González (Author) FEUP; Noélia Calvar (Author) FEUP; Emilia Tojo (Author) Other; Ángeles Domínguez (Author) Other

Journal

Title: Journal of Chemical & Engineering Data

Vol. 51

Pages: 2096-2102

ISSN: 0021-9568

Publisher: American Chemical Society

Indexing

ISI Web of Science

Scopus - 253 Citations

Scientific classification

FOS: Engineering and technology

CORDIS: Technological sciences

Other information

Authenticus ID: P-008-PCC

DOI: 10.1021/je060228n

Abstract (EN): This paper reports on the synthesis and the physical properties of the ionic liquid 1-ethyl-3-methylimidazolium ethylsulfate (EMISE). Experimental densities, speeds of sound and refractive indices were determined from (288.15 to 343.15) K. Dynamic viscosities were measured from (298.15 to 343.15) K and surface tension were measured from (288.15 to 313.15) K for pure ionic liquid. Densities, dynamic viscosities, speeds of sound, and isentropic compressibilities have been determined over the whole composition range for ethanol (1) + EMISE (2) and water (1) + EMISE (2) binary systems at T = (298.15, 313.15, and 328.15) K and atmospheric pressure. Excess molar volumes, viscosity deviations, and deviations in isentropic compressibility for the binary systems were fitted to a Redlich-Kister equation to determine the fitting parameters and the root mean square deviations. Refractive indices were measured at 298.15 K over the whole composition range for the ethanol (1) + EMISE (2) and water (1) + EMISE (2) binary systems. The results were used to calculate deviations in the refractive index. © 2006 American Chemical Society.

Language: English

Type (Professor's evaluation): Scientific