Abstract (EN):
The knowledge of the biodegradation kinetics of petroleum products in a contaminated soil is very important for the comprehension of the mechanisms involved, as well as for an effective design of the selected technologic variant. Laboratory studies were conducted using bioreactors containing two types of contaminated sandy soil samples: one with diesel and another with crude oil. Both were collected in spillages locations. The microbial activity was stimulated through aeration and addition of a solution enriched in nutrients. The soils were sampled every week in order to determine the pH, the moisture content, the bacterial population, the nutrients and the contaminant concentration. The degradation rates were quantified based upon changes in the total petroleum hydrocarbons (TPH) concentrations. The experimental data provided the basis for the development of a comprehensive model describing simultaneously the time evolution of biomass and contaminant degradation. Several phenomena were globally taken into account in the kinetic models: the volatilisation, a fast kinetics component, a slow kinetic component and the refractory hydrocarbons for the time scale used in the experiments. This model is in turn linked to the kinetics of the biomass evolution. The proposed methodology is hereby exemplified by its application to the crude oil sample.
Language:
Portuguese
Type (Professor's evaluation):
Scientific
No. of pages:
5