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The influence of equilibrium chemical reactions on vapor-liquid phase diagrams

Title
The influence of equilibrium chemical reactions on vapor-liquid phase diagrams
Type
Article in International Scientific Journal
Year
1988
Authors
barbosa, d
(Author)
FEUP
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doherty, mf
(Author)
Other
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Journal
Vol. 43
Pages: 529-540
ISSN: 0009-2509
Publisher: Elsevier
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Scientific classification
CORDIS: Technological sciences > Engineering > Chemical engineering
FOS: Engineering and technology > Chemical engineering
Other information
Authenticus ID: P-008-NQ4
Abstract (EN): Phase diagrams for simultaneous chemical reaction and phase equilibrium are presented for ideal and non-ideal systems. It is shown that reactive-azeotropes can occur even for ideal mixtures. The conditions for formation of reactive-azeotropes in constant-volatility systems are derived. These conditions show that for such systems reactive-azeotropes can occur only when the volatilities of the reactants are either all higher or all lower than the volatilities of the products. © 1988.
Language: English
Type (Professor's evaluation): Scientific
No. of pages: 12
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