Application of [EMpy][ESO4] ionic liquid as solvent for the liquid extraction of xylenes from hexane

• Type: Article in International Scientific Journal
• Date: 2010

Authors

Emilio J. González (Author) FEUP; Begoña González (Author) FEUP; Noélia Calvar (Author) FEUP; Ángeles Domínguez (Author) Other

Journal

Title: Fluid Phase Equilibria

Vol. 295 No. 2

Pages: 249-254

ISSN: 0378-3812

Publisher: Elsevier

Indexing

ISI Web of Science

Scopus

COMPENDEX

Scientific classification

FOS: Engineering and technology > Chemical engineering

CORDIS: Technological sciences

Other information

DOI: 10.1016/j.fluid.2010.05.017

Abstract (EN): Liquid–liquid equilibrium (LLE) data for the ternary systems {hexane + o-xylene + 1-ethyl-3-methylpyridinium ethylsulfate}, {hexane + p-xylene + 1-ethyl-3-methylpyridinium ethylsulfate}, and {hexane + m-xylene + 1-ethyl-3-methylpyridinium ethylsulfate} were determined at T = 298.15 K and atmospheric pressure. Selectivity, percent removal of aromatic, and solute distribution ratio, derived from the experimental equilibrium data, were used to determine if this ionic liquid can be used as a potential extracting solvent for the separation of xylenes from hexane. The consistency of tie-line data was ascertained by applying the Othmer–Tobias equation. The phase diagrams for the ternary systems are shown, and the tie-lines correlated with the NRTL model have been compared with the experimental data.

Language: English

Type (Professor's evaluation): Scientific