Mixture effects during the oxidation of toluene, ethyl acetate and ethanol over a cryptomelane catalyst

• Type: Article in International Scientific Journal
• Date: 2011

Authors

Vera Santos (Author) FEUP; M. F. R. Pereira (Author) FEUP; J. J. M. Orfão (Author) FEUP; J. L. Figueiredo (Author) FEUP

Journal

Title: Journal of Hazardous Materials

Vol. 185

Pages: 1236-1240

ISSN: 0304-3894

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 20 Citations

ISI Web of Science

Scopus - 31 Citations

Scientific classification

FOS: Engineering and technology > Chemical engineering

Other information

Authenticus ID: P-002-VRD

DOI: 10.1016/j.jhazmat.2010.10.036

Abstract (EN): The catalytic oxidation of two-component VOC mixtures (ethanol, ethyl acetate and toluene) was studied over cryptomelane. Remarkable mixture effects were observed on the activity and the selectivity. Toluene inhibits both ethyl acetate and ethanol oxidation, this effect being more evident in the case of ethyl acetate. For instance, the temperature for 100% conversion is about 210 degrees C when ethyl acetate is oxidised alone, and 250 degrees C or higher, when it is oxidised in mixtures with toluene. On the contrary, toluene oxidation is only slightly inhibited by the presence of ethyl acetate, while the presence of ethanol has a promoting effect. Concerning the mixtures of ethyl acetate and ethanol, both compounds have a mutual inhibitory effect, which is more evident in the case of ethyl acetate (the temperature for 100% conversion of ethyl acetate is about 45 degrees C higher when ethyl acetate is oxidised in mixtures with ethanol, while in the case of ethanol the corresponding increase is only 10 degrees C).

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 5