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A ternary phase in Cu-Li-Mg system

Title
A ternary phase in Cu-Li-Mg system
Type
Article in International Scientific Journal
Year
2007
Authors
M. H. Braga
(Author)
FEUP
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J. Ferreira
(Author)
Other
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L. F. Malheiros
(Author)
FEUP
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Journal
Vol. 436 No. 1-2
Pages: 278-284
ISSN: 0925-8388
Publisher: Elsevier
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Publicação em ISI Web of Science ISI Web of Science
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Scientific classification
FOS: Natural sciences > Physical sciences
CORDIS: Physical sciences > Physics
Other information
Authenticus ID: P-004-9CT
Abstract (EN): A previous study on Cu¿Li¿Mg system pointed out the existence of Cu8Li2Mg15, with an orthorhombic structure. The authors of the present paper also detected the existence of a ternary phase similar to the one mentioned. Due to some doubts on the phase¿s structure, a study of Cu¿Li¿Mg was focused in an area near to the composition of that phase. SEM/EDS measurements of the phases¿ compositions in equilibrium, as well as XRD powder patterns were obtained at room temperature. It was concluded that the ternary phase in Cu¿Li¿Mg system corresponds to CuMg2¿xLix (x¿0.11), with a hexagonal structure, space group P6222 (1 8 0), and lattice parameters a = b = 0.5260 nm, and c = 1.3649 nm. The structure was refined by Rietveld method; a Bragg reliability factor RB = 6.36% was obtained. Similarities between CuMg2¿xLix (x¿0.11) and NiMg2(H, D)x (x¿0.3) structures are detailed.
Language: English
Type (Professor's evaluation): Scientific
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