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Photochemical and photocatalytic degradation of trans-resveratrol

Title
Photochemical and photocatalytic degradation of trans-resveratrol
Type
Article in International Scientific Journal
Year
2013
Authors
Judith Monteiro
(Author)
Other
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Rita R N Marques
(Author)
Other
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Cristina Martinez
(Author)
Other
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Moises Canle L
(Author)
Other
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Journal
Vol. 12
Pages: 638-644
ISSN: 1474-905X
Publisher: Springer Nature
Indexing
Scientific classification
FOS: Natural sciences > Chemical sciences
Other information
Authenticus ID: P-005-3MB
Abstract (EN): Photochemical and photocatalytic degradation of the emerging pollutant trans-resveratrol has been studied under different irradiation wavelengths and using different TiO2 catalysts. trans-Resveratrol was more easily degraded when irradiated using the whole spectral range (UV-Vis) rather than with UV and near-UV to visible irradiation. The main intermediate of trans-resveratrol phototransformation was identified as its isomer cis-resveratrol. Different TiO2 catalysts were used to carry out the photocatalytic degradation of trans-resveratrol. Catalysts properties such as crystallite dimensions, surface area and presence of hydroxy surface groups are shown to be crucial to the photocatalytic efficiency of the materials tested. From the point of view of trans-resveratrol abatement, the photocatalytic process was more efficient than the pure photochemical one resulting in higher degradation rates and higher organic content removal. Six photoproducts of trans-resveratrol phototransformation were identified mainly resulting from the attack of the hydroxyl radical to the organic molecule.
Language: English
Type (Professor's evaluation): Scientific
Contact: cgsilva@fe.up.pt; mcanle@udc.es
No. of pages: 7
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