Optimization of N2O decomposition activity of CuO-CeO2 mixed oxides by means of synthesis procedure and alkali (Cs) promotion

• Type: Article in International Scientific Journal
• Date: 2018

Authors

Sónia A. C. Carabineiro (Author) FEUP; Maria Lykaki (Author) Other; Eleni Papista (Author) Other; Pedro B. Tavares (Author) Other; Michalis Konsolakis (Author) Other

Journal

Title: Catalysis Science and Technology

Vol. 8 No. 9

Pages: 2312-2322

ISSN: 2044-4753

Publisher: Royal Society of Chemistry

Indexing

ISI Web of Science

Scopus

INSPEC

Scientific classification

CORDIS: Technological sciences > Engineering > Chemical engineering

FOS: Engineering and technology > Chemical engineering

Other information

DOI: 10.1039/C8CY00316E

Abstract (EN): The fine-tuning of local surface chemistry of CuO-CeO2 mixed oxides by means of synthesis procedure and alkali promotion towards the rational design of highly active catalysts is investigated. In particular, the impact of alkali (Cs) promotion on the N2O decomposition activity (deN(2)O process) of CuO-ceria mixed oxides, pre-optimized through the preparation procedure (co-precipitation among different synthesis routes), is explored. It was found that the co-optimization of the synthesis procedure (co-precipitation) and alkali loading (1.0 at Cs per nm(2)) can boost the decomposition of N2O and resistance to O-2 inhibition, offering a half-conversion temperature (T-50) ca. 200 degrees C lower, when compared to a reference CuO-CeO2 sample. A complementary characterization study involving surface area determination (BET method), pore size distribution (BJH method), X-ray diffraction (XRD), H-2 temperature-programmed reduction (H-2-TPR) and X-ray photoelectron spectroscopy (XPS) was undertaken to gain insight into structure-property relationships. The results revealed that the superiority of Cs-doped samples can be mainly attributed to the electronic effect of the alkali promoter towards the stabilization of partially reduced Cu+/Ce3+ pairs, which play a key role in the deN(2)O process following a redox-type mechanism.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 11