Resumo (PT):
Abstract (EN):
mammalian fats) by enzymatic esterification, when applied at industrial scale in a Portuguese company,
and determines its carbon and water footprints as a measure of its potential environmental impact. Cost
and revenue data were obtained from real industrial and commercial sources, complemented with
literature and life cycle inventory data for the environmental impact calculations. Based on esterification
experiments, for optimizing operating conditions and enzymes selection, two scenarios are analyzed in
this work, using ethanol 96% (v/v) as reagent, and the following enzymes commercialized by Novozymes
as catalyst: (1) Lipozyme® CALB L for fish oil and mammalian fat and Novozym® 435 for poultry fat; (2)
Lipozyme® TL 100L for fish oil and Lecitase® Ultra for mammalian fat. Results show that under current
conditions the new process for the fats acidity reduction is not economically viable. To be feasible the
cost of enzymes should decrease to at least 9.75 V/kg and 1 V/kg for treating, respectively, the fish oil and
the mammalian fat. Alternatively, the sale price of fish oil alone and of fish oil and mammalian fat
together, should increase at least 3 and 4% respectively, to ensure that the process is cost effective. For the
process operating conditions defined in this work, it is estimated a carbon and water footprints of,
respectively, 1.3 t CO2 eq/t fat and 574 m3 water/t fat for the new esterification process, corresponding to
minor increases in the footprints of the current company processes.
Language:
English
Type (Professor's evaluation):
Scientific
No. of pages:
9