Standard molar enthalpies of formation of nine fluorinated beta-diketones by rotating bomb calorimetry

• Type: Article in International Scientific Journal
• Date: 1997

Authors

da Silva, MAVR (Author) FCUP; Goncalves, JM (Author) FCUP; Pilcher, G (Author) Other

Journal

Title: Journal of Chemical Thermodynamics

Vol. 29

Pages: 253-260

ISSN: 0021-9614

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 55 Citations

Scopus - 57 Citations

Other information

Authenticus ID: P-001-BWA

Abstract (EN): The standard enthalpies of formation of the following fluorinated beta-diketones at T = 298.15 K were determined from their enthalpies of combustion measured using rotating bomb calorimetry. [GRAPHICS] With enthalpies of vaporization and sublimation, the enthalpies of formation of these beta-diketones were derived for the gaseous state in their enol and keto forms. Where applicable, the enthalpies of formation in the gaseous state correlated satisfactorily with values estimated by group additivity methods. (C) 1997 Academic Press Limited.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 8