Abstract (EN):
Denitrification kinetics of a synthetic substrate containing molasses, sodium nitrate. Na2HPO4·12H2O, KH2PO4 and tap water treated with Na2SO3 was studied in a rotating disk biofilm reactor (RDBR). Experiments were performed at various conditions: biofilm thickness in the range 100-1100 ¿m and nitrate concentration in the feed of 5 to 50 mg N l-1. Biofilm density decreases with increasing biofilm thickness. Most experiments were in the kinetic controlled regime or fully penetrated biofilms. The intrinsic zero-order kinetic constant was found to be ko = 7.96 × 10-6 kg NO3-N*kg biofilm-1 s-1 (at 25°C). Some runs were in the diffusion controlled regime or partially penetrated biofilms; the effective diffusivity of nitrate in the biofilm which fitted experimental results was Db = 1.5 × 10-9 m2 s-1. The efficiency of the RDBR, considered as a CSTR, predicted by a model based on a zero-order reaction and diffusion inside the biofilm, reasonably agrees with experimental data.
Language:
English
Type (Professor's evaluation):
Scientific