Abstract (EN):
A1TUD-1, a new mesoporous, Bronsted acidic aluminosilicate with ideal characteristics for catalyst immobilization was used for the noncovalent anchoring of hydride tungsten complex [WH(2)(eta(2)-OOCCH(3)) (Ph(2)PCH(2)CH(2)PPh(2))(2)][ BPh(4)]. The immobilization was carried out by an adsorption process in liquid phase. The new materials were characterized by several techniques: spectroscopic methods (ICP-AES, FT-IR and UV/Vis), X-ray techniques (XPS and XRD), isothermal nitrogen adsorption and elemental analysis.
Language:
English
Type (Professor's evaluation):
Scientific
No. of pages:
8