Abstract (EN):
In this study the application of a sequential selective system that combined biosorption with biodegradation was evaluated as a feasible process for the removal of Cr(VI) and m-cresol from effluents. Cr(VI) biosorption on pretreated chestnut shells showed 100% metal removal and modelling efforts demonstrated that the pseudo-second order kinetic model and Langmuir isotherm fit well the process behaviour. Thus, the treated stream was an appropriate environment for the biodegradation of m-cresol using a laccase-producer fungus, Phlebia radiata. Two bioreactor configurations, rotating drum and modified-airlift, were studied using the fungus grown on chestnut shells, which act as support-substrate as well as oxidative enzyme inductor increasing the laccase activity up to 1000 U L-1. The best bioreactor, rotating drum, reached 100% removal in 7 days. Finally, the best configuration for the sequential selective system was modelled operating in continuous mode by the breakthrough curves generated using FASTv2.0 and the design bioreactor flow model.
Language:
English
Type (Professor's evaluation):
Scientific
No. of pages:
9