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HEAT-CONDUCTION CALORIMETERS - TIME CONSTANTS, SENSITIVITY AND FAST TITRATION EXPERIMENTS

Title
HEAT-CONDUCTION CALORIMETERS - TIME CONSTANTS, SENSITIVITY AND FAST TITRATION EXPERIMENTS
Type
Article in International Scientific Journal
Year
1994
Authors
BACKMAN, P
(Author)
Other
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Bastos, M
(Author)
FCUP
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HALLEN, D
(Author)
Other
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LONNBRO, P
(Author)
Other
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WADSO, I
(Author)
Other
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Journal
Vol. 28
Pages: 85-100
ISSN: 0165-022X
Publisher: Elsevier B.V.
Other information
Authenticus ID: P-00G-92F
Abstract (EN): Seven heat conduction calorimeters have been evaluated in terms of sensitivity and thermal response time. The use of a dynamic method to correct for the thermal inertia of the calorimeter is shown to reduce by one order of magnitude the time required to conduct a stepwise titration experiment involving a fast reaction. The ability to determine association constants of strong 1:1 complexes has been evaluated in terms of the precision of determining thermal energy.
Language: English
Type (Professor's evaluation): Scientific
No. of pages: 16
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