HEAT-CONDUCTION CALORIMETERS - TIME CONSTANTS, SENSITIVITY AND FAST TITRATION EXPERIMENTS
Type
Article in International Scientific Journal
Year
1994
Authors
BACKMAN, P
(Author)
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LONNBRO, P
(Author)
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WADSO, I
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Abstract (EN):
Seven heat conduction calorimeters have been evaluated in terms of sensitivity and thermal response time. The use of a dynamic method to correct for the thermal inertia of the calorimeter is shown to reduce by one order of magnitude the time required to conduct a stepwise titration experiment involving a fast reaction. The ability to determine association constants of strong 1:1 complexes has been evaluated in terms of the precision of determining thermal energy.
Language:
English
Type (Professor's evaluation):
Scientific
No. of pages:
16
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A SYSTEM OF MICROCALORIMETERS (1994) Article in International Scientific Journal
BACKMAN, P; Bastos, M; BRIGGNER, LE; HAGG, S; HALLEN, D; LONNBRO, P; NILSSON, SO; OLOFSSON, G; SCHON, A; SUURKUUSK, J; TEIXEIRA, C; WADSO, I